Gulf of Mexico Nutrient Sensor Pilot


The Alliance for Coastal Technologies (ACT), is a NOAA-funded partnership or the academe, resource managers, and private sectorto foster developemnt and adoption of reliable sensors for use in monitoring coastal, freshwater and ocean environments. As part of the Alliance for Coastal Technologies (ACT), the Gulf of Mexico Nutrient Sensor Pilot Project aims to evaluate the "operational status" of newly commercially available nutrient sensors through integration into existing monitoring programs. Operational status is being evaluated through a combination of factors, including logistics required for deployment; ease of integration into shared data management systems; operation and maintenance schedules and requirements; and quality of data. These activities support the ongoing efforts in ACT, including the interagency Nutrient Sensor Challenge, to advance nutrient sensing in critical ecosystems, such as the northern Gulf of Mexico. With funding from NOAA through ACT and the Gulf of Mexico Coastal Ocean Observing System (GCOOS), researchers at University of Louisiana at Lafayette are coordinating with partners at the University of Texas Marine Science Institute, the Louisiana Universities Marine Consortium, Dauphin Island Sea Lab, Sanibel-Captiva Conservation Foundation, and the USGS in Tampa Bay to build a network of continuous nitrate sensors in coastal and estuarine ecosystems around the northern Gulf of Mexico.

These activities support the ongoing efforts in ACT, including the interagency Nutrient Sensor Challenge, to advance nutrient sensing in critical ecosystems, such as the northern Gulf of Mexico. With funding from NOAA through ACT and the Gulf of Mexico Coastal Ocean Observing System (GCOOS), researchers at University of Louisiana at Lafayette are coordinating with partners in TX, LA, AL, and FL to build a network of continuous nitrate sensors in coastal and estuarine ecosystems around the northern Gulf. 

Disclaimer

These data are preliminary and may be revised upon further analysis. They are being provided as a demonstration of the capabilities and integration of this nutrient sensor, as an educational tool, and to engage the public.

 

The Data Stream

Sensor Deployment: SCCF RECON

{NOTE: Highlight area to zoom and double-click graph to return to default view.}


NO2+NO3



Water Temperature



CDOM



Conductivity



Turbidity



Salinity



Sensor Depth



Dissolved Oxygen (Saturated)



Dissolved Oxygen



Chlorophyll



 

Gulf of Mexico Partners

 

Project Implementation

 

The Solution

WIZ: Portable in situ Probe for Water Analysis

by SYSTEA SpA

This portable probe for water analysis was used to measure time series of:

  • Ammonia (N-NH3)
  • Orthophosphate (P-PO4)
  • Nitrate + nitrite N-(NO3+NO2)
  • Nitrite (N-NO2)
  • Total Phosphorous (P)
  • Total Nitrogen (N)
  • COD/TOC
  • BOD

The package included Control Panel (WCP) software the allows to users to setup any WIZ probe, using an RS-232 serial port; it can be used even remotely trough a GSM modem. Also, it included Zetalog and Zetaced packages that allows to use WIZ at the higher level. Zetalog turn on WIZ just before the measurement cycle and turn it off as soon completed allowing power saving. Data are sent trough GPRS to Zetaced, running on a web server, where are logged and can be retrieved, validated and displayed as table or graphics trend.

 

Features of Interest

  • Multiparametric: up to 4 parameters in the same unit.
  • Flexibility: more than 10 multiparametric configuration already developed active methods selectable by control software.
  • Low reagents consumption: few uL of reagents per analysis.
  • Low electrical consumption: battery operated
  • Deployment Kit: including buoy, warning lamp, batteries, batteries charger and solar panels available as option
  • Reagent canister: easy to plug in, new reagent set can be plug on site w/o WIZ removal
  • Quick start up: delivered fully tested and calibrated as per end user specifications, just fill the reagent canister and power to start up
  • Autowash/Autocleaning: self wash and/or cleaning at the end of each measurement.
  • Control Software: easy to use and to learn; short training, specifically designed for chemists.
  • QC control: programmable QC check while deployed.
  • Filter options: wide range of filter options, 10/25/100/400uM self cleaning or not or 0.25uM microfilter, self purging
  • Control options: integrated firmware and internal data logging, data retrieve by PC software, external data logger for power On and OFF, analysis frequency, GPRS data transmission to control center. Remote control by combined use of Zetalog and Zetaced.
 Technology   µLFR* Technology, Batch, sequential for all MP versions
 Applications   Hydrology/Water Resources/Coastal monitoring
 Measurements frequency    Programmable
 Cycle time    MP4 Nutrients, 40 minutes, for a complete cycle, other configurations from 40 to 60 minutes.
 Samples preheating    Yes
 Max number of reagents    8 reagents + QC check solution and Wash solution
 Reagent stability    4-10 weeks, depending on the water temperature
 Deployment time    Up to 2.5 months
 Body material    PVC
 Max depth    -10m
 Operating temperature    4° - 40°C
 Wastes    n. 1 x 5L bag for wastes containing reagents, free waste for washings with DI Water & Sample
 Flow cell type    Quartz 4 measuring sides: 10mm x 2.5mm
 Detectors   Standard Colorimetric methods: multi-beam fiber optic colorimeter with silicon detector; Fluorimetric methods: LED/filters: Ex./Em. at specific wavelength;  Turbidimetric: scattering at 800nm; COD UV: LED 254nm corrected at 525nm; TN/NO3 UV: Xenon flash lamp, filters 220 and 270nm 
 Detector technology    LED/LED UV/UV filters
 Reading methods    Absorbance/Fluorimetry/UV/Nephelometry
 Reduction Module for NO3   Yes by UV photoreduction
 WIZ Control Panel Software    Compatible with Windows XP, 7.0 & 8.0 (lates version, not tested), WIZ setup and operations, data download to computer
 QC solution    Concentrated for long term stability, diluted on line when required
 Off scale sample dilution and reanalyze    Yes
 Automated sample spike    Yes
 Calibration    Automated after reagent replacement
 Power supply    12VDC
 Power requirements    3W in Stand By, 8W (average) during analysis, max 1.5A; MP4 standard 0.46Ah
 Dimensions    Analytical unit: 140mm (diameter) x 535mm (height) Reagent canister (standard): 70mm (diameter) x 230mm (height)
 Connector    Submergible male 6 poles for RS232 and 12VDC power
 Cable    Submergible Standard length 10m female connector
 Data output    RS232
 Filtration options    10/25/100/400uM with or w/o self cleaning, 0.25uM self purging microfilter
 Standard package    WIZ probe - Reagents canister standard (Enlarged version on request) - 12 VDC power supply for maintenance and setup - Reagent bag filling tool - 10 m submergible cable - Carrying case - Wiz control panel software license - Start-up kit
 Options    Customized cable length; Enlarged Reagent Canister; Zetalog - Zetaced setup and license
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